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2Na + Cl2 2NaCl

Synthesis of sodium chloride — balanced chemical equation, step by step.

Balanced equation
2Na + Cl2 2NaCl
Synthesis reaction

This is the formation of ordinary table salt from its highly reactive elements.

How to balance Na + Cl2 = NaCl

A synthesis (combination) reaction joins two or more reactants into a single product. Balancing means choosing coefficients so that every element has the same number of atoms on both sides of the arrow — the Law of Conservation of Mass. Here is how it's done, step by step.

Step 1 — Write the unbalanced equation

Start with the correct formulas for every reactant and product:

Na + Cl2 = NaCl

Step 2 — Count the atoms of each element

With no coefficients yet (everything counted once), the atoms do not match. The ✗ marks show which elements are unbalanced:

ElementReactantsProductsEqual?
Na11
Cl21

Step 3 — Add the smallest whole-number coefficients

Adjust the coefficients in front of each formula until every element balances. The smallest whole-number coefficients are 2 Na, 1 Cl2, 2 NaCl, giving:

2Na + Cl2 = 2NaCl

For a synthesis reaction, balance the element that appears in only one reactant and one product first, then adjust the remaining free elements.

Step 4 — Verify the balance

Recount every element. Each one now matches on both sides:

ElementReactantsProductsBalanced
Na22
Cl22

All elements are balanced and the coefficients are the smallest whole numbers, so 2Na + Cl2 = 2NaCl is the correct balanced equation.

Molar masses and mole ratio

The balanced coefficients are also the mole ratio of the reaction. Using standard atomic masses, the molar mass of each substance is:

SubstanceRoleMolar mass (g/mol)Moles
Nareactant22.992
Cl2reactant70.91
NaClproduct58.442

For this reaction the mole ratio is 2 : 1 : 2. Combine these molar masses with the ratio in the free stoichiometry calculator to convert between moles, grams, and the number of particles for any reactant or product.

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