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Zn + 2HCl ZnCl2 + H2

Zinc and hydrochloric acid — balanced chemical equation, step by step.

Balanced equation
Zn + 2HCl ZnCl2 + H2
Single replacement reaction

This is the classic laboratory method for generating hydrogen gas.

How to balance Zn + HCl = ZnCl2 + H2

In a single-replacement reaction, one element displaces another from a compound. Balancing means choosing coefficients so that every element has the same number of atoms on both sides of the arrow — the Law of Conservation of Mass. Here is how it's done, step by step.

Step 1 — Write the unbalanced equation

Start with the correct formulas for every reactant and product:

Zn + HCl = ZnCl2 + H2

Step 2 — Count the atoms of each element

With no coefficients yet (everything counted once), the atoms do not match. The ✗ marks show which elements are unbalanced:

ElementReactantsProductsEqual?
Zn11
H12
Cl12

Step 3 — Add the smallest whole-number coefficients

Adjust the coefficients in front of each formula until every element balances. The smallest whole-number coefficients are 1 Zn, 2 HCl, 1 ZnCl2, 1 H2, giving:

Zn + 2HCl = ZnCl2 + H2

For a single-replacement reaction, balance the element being displaced first, then balance the spectator ions, and finish with any free element or hydrogen gas.

Step 4 — Verify the balance

Recount every element. Each one now matches on both sides:

ElementReactantsProductsBalanced
Zn11
H22
Cl22

All elements are balanced and the coefficients are the smallest whole numbers, so Zn + 2HCl = ZnCl2 + H2 is the correct balanced equation.

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