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S + O2 SO2

Synthesis of sulfur dioxide — balanced chemical equation, step by step.

Balanced equation
S + O2 SO2
Synthesis reaction

Sulfur dioxide is released when sulfur-containing fuels burn and is a primary cause of acid rain.

How to balance S + O2 = SO2

A synthesis (combination) reaction joins two or more reactants into a single product. Balancing means choosing coefficients so that every element has the same number of atoms on both sides of the arrow — the Law of Conservation of Mass. Here is how it's done, step by step.

Step 1 — Write the unbalanced equation

Start with the correct formulas for every reactant and product:

S + O2 = SO2

Step 2 — Count the atoms of each element

Counting the atoms on each side, every element already matches — so each coefficient is 1:

ElementReactantsProductsEqual?
S11
O22

Step 3 — Add the smallest whole-number coefficients

Adjust the coefficients in front of each formula until every element balances. The smallest whole-number coefficients are 1 S, 1 O2, 1 SO2, giving:

S + O2 = SO2

For a synthesis reaction, balance the element that appears in only one reactant and one product first, then adjust the remaining free elements.

Step 4 — Verify the balance

Recount every element. Each one now matches on both sides:

ElementReactantsProductsBalanced
S11
O22

All elements are balanced and the coefficients are the smallest whole numbers, so S + O2 = SO2 is the correct balanced equation.

Molar masses and mole ratio

The balanced coefficients are also the mole ratio of the reaction. Using standard atomic masses, the molar mass of each substance is:

SubstanceRoleMolar mass (g/mol)Moles
Sreactant32.061
O2reactant321
SO2product64.061

For this reaction the mole ratio is 1 : 1 : 1. Combine these molar masses with the ratio in the free stoichiometry calculator to convert between moles, grams, and the number of particles for any reactant or product.

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